Photo: Jeffrey Mayer/Wireimage
Nashville darling Reese Witherspoon first charmed audiences in 1991 with her role in the summer flick The Man in the Moon. More than 20 years later, we're still smitten by her classic Southern allure. Here, photographed just before snagging the Oscar for playing fellow iconic Tennessean June Carter Cash in 2005's Walk the Line, Reese is radiant with her trademark smile; soft, upswept hair; and rosy cheeks. Like any true Southern lady, this actress and producer is effortlessly stunning on and off the red carpet.